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III. fn I o n i z a t i o n s . . . . . . . . . . . . . . . . . . . . . IV. T r e n d s in C y c l o p e n t a d i e n y l e l I o n i z a t i o n s . . . . . . . . . . . . . 64 64 67 67 69 69 69 70 D. B i s - ~ - C y c l o p e n t a d i e n y l Metal C o m p l e x e s . . . . . . . . . . . . . . . 71 I. II. III. IV. M(r~-CsHs)2(CO) n . . . . . . . . . . . . . . . . . . . . M(n-CsHs)2Hn ........................................

3. V a r i a t i o n w i t h Metal . . . . . . . . . . . . . . . . . . VIII. B a n d I n t e n s i t i e s . . . . . . . . . . . . . . . . . . . . IX. L i g a n d F i e l d T r e a t m e n t s o f S a n d w i c h C o m p o u n d s . . . . . . . . . . 57 58 58 58 59 59 59 60 60 61 62 63 C. L a n t h a n i d e a n d A c t i n i d e C y c l o o e t a t e t r a e n e a n d C y c l o p e n t a d i e n y l C o m p o u n d s . .

There are three methods used for calculating ionization energies which are described below. III. Some Methods o f Calculating Ionization Energies 1. ) or other calculations are carried out on the molecular ground state and on the relevant ionic states, and the calculated energy differences are compared with experimental ionization energies. F. calculations this is termed the 2xSCF method. 2. F. E. = - e i . F. method (such as neglect of electron correlation and relativistic effects), it assumes that the molecular orbitats are the same for the molecule and the molecular ion.

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